It doesn’t matter where you place the trytond.conf, just use an absolute path. Examples:
Running with absolute path:
(tryton) E:\tryton>python Scripts\trytond-admin -c E:\tryton\Scripts\trytond.conf -d tryton --all -vv
Running with relative path:
It’s important where you are in the directory tree. In this case you are in E:\tryton and you have placed your trytond.conf in the Scripts directory.
(tryton) E:\tryton>python Scripts\trytond-admin -c Scripts\trytond.conf -d tryton --all -vv
I’ve done this of the top of my head so it’s not tested. If it isn’t working try different things you won’t break anything.